Reactivity of phosphine oxide H<inf>3</inf>PO in the reactions with ketones

Babaev V.; Khayarov K.; Yakhvarov D.; Rizvanov I.; Pavlov P.; Badeeva E.; Zinnatullin R.; Gorbachuk E.

Reactivity of phosphine oxide H<inf>3</inf>PO in the reactions with ketones

Gorbachuk E.; Badeeva E.; Babaev V.; Rizvanov I.; Zinnatullin R.; Pavlov P.; Khayarov K.; Yakhvarov D.

URI: https://dspace.kpfu.ru/xmlui/handle/net/143454

Date: 2016

Abstract:

© 2016, Springer Science+Business Media New York.The reactivity of the electrochemically generated phosphine oxide H3PO towards ketones (acetone, ethyl methyl ketone, methyl n-propyl ketone, and tert-butyl methyl ketone) has been studied. It was found that this reaction led to the formation of mono- and bis(hydroxyalkyl)phosphine oxides of the formulas RRĆ(OH)P(O)H2 and [RRĆ(OH)]2P(O)H (R = Me; R´ = Me, Et, Pr) and represents the first example of the P—C bond formation involving the intermediate H3PO.

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.