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Reactivity of phosphine oxide H<inf>3</inf>PO in the reactions with ketones
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| dc.contributor.author | Gorbachuk E. | |
| dc.contributor.author | Badeeva E. | |
| dc.contributor.author | Babaev V. | |
| dc.contributor.author | Rizvanov I. | |
| dc.contributor.author | Zinnatullin R. | |
| dc.contributor.author | Pavlov P. | |
| dc.contributor.author | Khayarov K. | |
| dc.contributor.author | Yakhvarov D. | |
| dc.date.accessioned | 2018-09-19T20:56:49Z | |
| dc.date.available | 2018-09-19T20:56:49Z | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 1066-5285 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/143454 | |
| dc.description.abstract | © 2016, Springer Science+Business Media New York.The reactivity of the electrochemically generated phosphine oxide H3PO towards ketones (acetone, ethyl methyl ketone, methyl n-propyl ketone, and tert-butyl methyl ketone) has been studied. It was found that this reaction led to the formation of mono- and bis(hydroxyalkyl)phosphine oxides of the formulas RRĆ(OH)P(O)H2 and [RRĆ(OH)]2P(O)H (R = Me; R´ = Me, Et, Pr) and represents the first example of the P—C bond formation involving the intermediate H3PO. | |
| dc.relation.ispartofseries | Russian Chemical Bulletin | |
| dc.subject | electrochemistry | |
| dc.subject | ESI mass spectrometry | |
| dc.subject | hydroxyalkylphosphine oxides | |
| dc.subject | ketones | |
| dc.subject | macroscale electrolysis | |
| dc.subject | NMR spectroscopy | |
| dc.subject | phosphine oxide H PO 3 | |
| dc.subject | white phosphorus | |
| dc.title | Reactivity of phosphine oxide H<inf>3</inf>PO in the reactions with ketones | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 5 | |
| dc.relation.ispartofseries-volume | 65 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 1289 | |
| dc.source.id | SCOPUS10665285-2016-65-5-SID85010636695 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.