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Reactivity of phosphine oxide H<inf>3</inf>PO in the reactions with ketones

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dc.contributor.author Gorbachuk E.
dc.contributor.author Badeeva E.
dc.contributor.author Babaev V.
dc.contributor.author Rizvanov I.
dc.contributor.author Zinnatullin R.
dc.contributor.author Pavlov P.
dc.contributor.author Khayarov K.
dc.contributor.author Yakhvarov D.
dc.date.accessioned 2018-09-19T20:56:49Z
dc.date.available 2018-09-19T20:56:49Z
dc.date.issued 2016
dc.identifier.issn 1066-5285
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/143454
dc.description.abstract © 2016, Springer Science+Business Media New York.The reactivity of the electrochemically generated phosphine oxide H3PO towards ketones (acetone, ethyl methyl ketone, methyl n-propyl ketone, and tert-butyl methyl ketone) has been studied. It was found that this reaction led to the formation of mono- and bis(hydroxyalkyl)phosphine oxides of the formulas RRĆ(OH)P(O)H2 and [RRĆ(OH)]2P(O)H (R = Me; R´ = Me, Et, Pr) and represents the first example of the P—C bond formation involving the intermediate H3PO.
dc.relation.ispartofseries Russian Chemical Bulletin
dc.subject electrochemistry
dc.subject ESI mass spectrometry
dc.subject hydroxyalkylphosphine oxides
dc.subject ketones
dc.subject macroscale electrolysis
dc.subject NMR spectroscopy
dc.subject phosphine oxide H PO 3
dc.subject white phosphorus
dc.title Reactivity of phosphine oxide H<inf>3</inf>PO in the reactions with ketones
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 65
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1289
dc.source.id SCOPUS10665285-2016-65-5-SID85010636695

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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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