Abstract:
A nickel-based catalyst precursor has been synthesized for in-situ upgrading of heavy crude oil that is capable of increasing the efficiency of steam stimulation techniques. The precursor activation occurs due to the decomposition of nickel tallate under hydrothermal conditions. The aim of this study is to analyze the efficiency of in-situ catalytic upgrading of heavy oil from laboratory scale experiments to the field-scale implementation in Boca de Jaruco reservoir. The proposed catalytic composition for in-reservoir chemical transformation of heavy oil and natural bitumen is composed of oil-soluble nickel compound and organic hydrogen donor solvent. The nickel-based catalytic composition in laboratory-scale hydrothermal conditions at 300°С and 90 bars demonstrated a high performance; the content of asphaltenes was reduced from 22% to 7 wt.%. The viscosity of crude oil was also reduced by three times. The technology for industrial-scale production of catalyst precursor was designed and the first pilot batch with a mass of 12 ton was achieved. A «Cyclic steam stimulation» technology was modified in order to deliver the catalytic composition to the pay zones of Boca de Jaruco reservoir (Cuba). The active forms of catalyst precursors are nanodispersed mixed oxides and sulfides of nickel. The pilot test of catalyst injection was carried out in bituminous carbonate formation M, in Boca de Jaruco reservoir (Cuba). The application of catalytic composition provided increase in cumulative oil production and incremental oil recovery in contrast to the previous cycle (without catalyst) is 170% up to date (the effect is in progress). After injection of catalysts, more than 200 samples from production well were analyzed in laboratory. Based on the physical and chemical properties of investigated samples and considering the excellent oil recovery coefficient it is decided to expand the industrial application of catalysts in the given reservoir. The project is scheduled on the fourth quarter of 2021.
