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Investigation of thermal behavior of mixed-valent iron borates vonsenite and hulsite containing [OM<inf>4</inf>]<sup>n+</sup>and [OM <inf>5</inf>] <sup>n+</sup>oxocentred polyhedra by in situ high-temperature Mössbauer spectroscopy, X-ray diffraction and thermal analysis 261

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Investigation of thermal behavior of mixed-valent iron borates vonsenite and hulsite containing [OM<inf>4</inf>]<sup>n+</sup>and [OM <inf>5</inf>] <sup>n+</sup>oxocentred polyhedra by in situ high-temperature Mössbauer spectroscopy, X-ray diffraction and thermal analysis 12 19 7 9 10 18 1

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