A new heterometallic pivalate {Fe<inf>8</inf>Cd} complex as an example of unusual "ferric wheel" molecular self-assembly

Zueva E.M.; Efimov N.N.; Ugolkova E.A.; Eremenko I.L.; Lutsenko I.A.; Sidorov A.A.; Imshennik V.K.; Petrova M.M.; Maksimov Y.V.; Lysenko K.A.; Kiskin M.A.

A new heterometallic pivalate {Fe<inf>8</inf>Cd} complex as an example of unusual "ferric wheel" molecular self-assembly

Lutsenko I.A.; Kiskin M.A.; Lysenko K.A.; Zueva E.M.; Efimov N.N.; Ugolkova E.A.; Maksimov Y.V.; Imshennik V.K.; Petrova M.M.; Sidorov A.A.; Eremenko I.L.

URI: https://dspace.kpfu.ru/xmlui/handle/net/162313

Date: 2020

Abstract:

© 2020 The Royal Society of Chemistry. The interaction of the pivalate complexes of iron(iii), [Fe3O(Piv)6(H2O)3]·HPiv, and cadmium(ii), [Cd(Piv)2], in Et2O resulted in one more type of "ferric wheel"family complex, namely [Fe8(Piv)16{Cd(Piv)2}(μ-OH)8]·Et2O (1). The complex is an octanuclear iron(iii) wheel with a {Cd(Piv)2} moiety asymmetrically incorporated into the ring.

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.