Two-Dimensional Coordination Polymer {[Bi(Рyz)I<inf>3</inf>]}: Structure and Analysis of the Packing Using the Hirshfeld Surface Method

Abstract

© 2020, Pleiades Publishing, Ltd. Abstract: The reaction of BiI3 with pyrazine in tetrahydrofuran affords the two-dimensional coordination polymer {[Bi(Pyz)I3]} (I), whose structure is determined by X-ray diffraction analysis (СIF file ССDС no. 1904990). The contributions of various interatomic contacts to the crystal packing of compound I are studied using the Hirshfeld surface analysis performed for the elementary unit of compound I. The interatomic distances I···H make the largest contribution to the crystal packing of compound I.