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Investigation of thermal behavior of mixed-valent iron borates vonsenite and hulsite containing [OM4]n+ and [OM5]n+ oxocentred polyhedra by in situ high-temperature Mossbauer spectroscopy, X-ray diffraction and thermal analysis Mixed-valent iron borates vonsenite and hulsite 433

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Investigation of thermal behavior of mixed-valent iron borates vonsenite and hulsite containing [OM4]n+ and [OM5]n+ oxocentred polyhedra by in situ high-temperature Mossbauer spectroscopy, X-ray diffraction and thermal analysis Mixed-valent iron borates vonsenite and hulsite 20 17 13 12 14 21 5

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