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(Et<inf>4</inf>N)[Mo<sup>III</sup>(DAPBH)Cl<inf>2</inf>], the first pentagonal-bipyramidal Mo(iii) complex with a N<inf>3</inf>O<inf>2</inf>-type Schiff-base ligand: manifestation of unquenched orbital momentum and Ising-type magnetic anisotropy 140

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(Et<inf>4</inf>N)[Mo<sup>III</sup>(DAPBH)Cl<inf>2</inf>], the first pentagonal-bipyramidal Mo(iii) complex with a N<inf>3</inf>O<inf>2</inf>-type Schiff-base ligand: manifestation of unquenched orbital momentum and Ising-type magnetic anisotropy 2 4 4 6 2 7 21

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