Triangular Clusters of Molybdenum Coordinated with Diethylthiocarbamate: Synthesis, Structure and Solution Behavior

Abstract

© 2018, Springer Science+Business Media, LLC, part of Springer Nature. Two novel clusters [Mo3S4(dtc)3(μ-dtc)(L)] (where L = (CD3)2SO and tetrahydrothiophene, tht) were prepared and structurally characterized. The tht complex and its previously reported congener with L = py were studied by means of temperature-dependent1H NMR spectroscopy, indicating order of lability tht ≫ py.