Mössbauer study of Се<inf>2</inf>Fe<inf>17</inf> compound in different magnetic states

Abstract

© 2018 Elsevier B.V. Mössbauer spectra of two samples of the Ce2Fe17 compound have been analyzed and hyperfine parameters, compared. The samples were subjected to different preparation techniques and display different magnetic properties. It is established that to well fit the Mössbauer spectra of these samples, an appropriate model should be used that takes into account an additional subspectrum differing in hyperfine parameters from the subspectra employed in conventional models. It is shown that in the ferromagnetic state, the samples contain local regions with an antiferromagnetic order, the volume fraction of which, being different for two samples, increases on approaching the temperature of ferro-to-antiferromagnet transition.