Аннотации:
© 2018, Springer Science+Business Media, LLC, part of Springer Nature. The results of a study of the composition of active forms of the catalyst formed upon degradation of the precursor, based on the results of physical modeling of a sample of high-viscosity oil having high asphaltene and resin contents, are presented. Oil-soluble iron, cobalt, and copper tallates were used as the objects of the study. The composition of the separated powder of the active form of the catalyst was determined by X-ray diffraction analysis, and the catalyst particle size was determined by scanning electron microscopy. The SARA (saturate, aromatic, resin and asphaltene) analysis data revealed a marked decrease in high-molecular-weight oil components due to thermocatalytic cracking. The basic transformation mechanism is breakdown of the high-molecular-weight compounds along the sulfur-bearing bonds, as indicated by elemental CHNS (carbon, hydrogen, nitrogen and sulfur) analysis data. It is shown that the cobalt- and copper-based oil-soluble complexes turn are converted to sulfide forms and the iron-based complex is converted to the oxide form. According to the results of scanning electron microscopic analysis of the catalyst, the particle size is about 60 nm.
