Аннотации:
© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.For the first time, monofunctionalized pillar[5]arenes containing a 1-aminophosphonate fragment have been obtained and characterized. As shown by NMR spectroscopy, the replacement of the amino groups by 1-aminophosphonate units in the macrocycle structure allows switching of “self-assembling-host-guest complexation” properties of the monofunctionalized pillar[5]arenes. Thus, new synthesized aminophosphonated pillar[5]arenes form host-guest complexes with aliphatic amines contrary to monoamine macrocycles that tend to self-assemble.