dc.contributor.author |
Gorbachuk E. |
|
dc.contributor.author |
Badeeva E. |
|
dc.contributor.author |
Babaev V. |
|
dc.contributor.author |
Rizvanov I. |
|
dc.contributor.author |
Zinnatullin R. |
|
dc.contributor.author |
Pavlov P. |
|
dc.contributor.author |
Khayarov K. |
|
dc.contributor.author |
Yakhvarov D. |
|
dc.date.accessioned |
2018-09-19T20:56:49Z |
|
dc.date.available |
2018-09-19T20:56:49Z |
|
dc.date.issued |
2016 |
|
dc.identifier.issn |
1066-5285 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/143454 |
|
dc.description.abstract |
© 2016, Springer Science+Business Media New York.The reactivity of the electrochemically generated phosphine oxide H3PO towards ketones (acetone, ethyl methyl ketone, methyl n-propyl ketone, and tert-butyl methyl ketone) has been studied. It was found that this reaction led to the formation of mono- and bis(hydroxyalkyl)phosphine oxides of the formulas RRĆ(OH)P(O)H2 and [RRĆ(OH)]2P(O)H (R = Me; R´ = Me, Et, Pr) and represents the first example of the P—C bond formation involving the intermediate H3PO. |
|
dc.relation.ispartofseries |
Russian Chemical Bulletin |
|
dc.subject |
electrochemistry |
|
dc.subject |
ESI mass spectrometry |
|
dc.subject |
hydroxyalkylphosphine oxides |
|
dc.subject |
ketones |
|
dc.subject |
macroscale electrolysis |
|
dc.subject |
NMR spectroscopy |
|
dc.subject |
phosphine oxide H PO 3 |
|
dc.subject |
white phosphorus |
|
dc.title |
Reactivity of phosphine oxide H<inf>3</inf>PO in the reactions with ketones |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
5 |
|
dc.relation.ispartofseries-volume |
65 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1289 |
|
dc.source.id |
SCOPUS10665285-2016-65-5-SID85010636695 |
|