Development of a method for introducing 1-aminophosphonate fragment in a siloxane matrix

Abstract

© 2016 Taylor & Francis Group, LLC.A versatile synthetic method for the preparation of 1-aminophosphonate derivatives of methylsiloxane oligomers was developed. The introduction of trimethylsilyl amino protecting groups promotes hydrosilylation. The proposed modeling technique allows entering 1-aminophosphonate fragment into the siloxane skeleton of the matrix structure, as well as into the hydrolytically unstable alkoxy-functionalized organosilicon compounds.