Conformational Analysis of 2-Chloro- N-[2-((Diphenylphosphoryl)Methyl)Phenyl]-Acetamide and 2-Chloro-N-[2-((Diphenylthiophosphoryl)Methyl)Phenyl]Acetamide

Abstract

Copyright © 2015 Taylor & Francis Group, LLC. The polarities of 2-chloro-N-(2-((diphenylphosphoryl)methyl)phenyl)acetamide and 2-chloro-N-(2-((diphenylthiophosphoryl)methyl)phenyl)acetamide were determined, and conformational analysis of these was carried out by the method of dipole moments and quantum chemical calculations. The formation of intramolecular hydrogen bond P=O⋯HN or P=S⋯HN in these acetamides is possible.