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dc.contributor.author | Fatkullin N. | |
dc.contributor.author | Kimmich R. | |
dc.date.accessioned | 2018-09-18T20:12:59Z | |
dc.date.available | 2018-09-18T20:12:59Z | |
dc.date.issued | 2006 | |
dc.identifier.issn | 1022-1360 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/137650 | |
dc.description.abstract | The paper deals with the question whether the tube/reptation model of polymer chain dynamics is compatible with general laws of statistical physics. Based on a relation between the mean squared fluctuation of the number of segments in a given volume element and the isothermal compressibility of the polymer system, it follows straightforwardly that the tube/reptation model predicts fluctuations larger than permitted by thermodynamics on the time scale t ≳ τR, where τR is the Rouse relaxation time. © 2006 WILEY-VCH Verlag GmbH & Co. KGaA. | |
dc.relation.ispartofseries | Macromolecular Symposia | |
dc.subject | Chain dynamics | |
dc.subject | Fluctuations | |
dc.subject | Polymer melts | |
dc.subject | Reptation | |
dc.subject | Thermodynamics | |
dc.title | Thermodynamic limitations of the reptation model | |
dc.type | Conference Paper | |
dc.relation.ispartofseries-volume | 237 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 69 | |
dc.source.id | SCOPUS10221360-2006-237-SID33744790327 |