Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion

Abstract

The volumes of electrostriction of the ions of lithium perchlorate are in a linear relation with the solvent electrostriction parameter ∂(1/ε)/∂p but the volume changes of ion pair transition state of electrophilic addition of aryl sulfenyl chloride to styrene and cyclohexene have the slope about 20 times less. © 2008.