Study of intra- and intermolecular interactions with participation of α-phosphorylated amines and alcohols in different solvents

Abstract

Specific interactions of α-hydroxy- and α-aminophosphonates in chloroform and pyridine solutions were studied by theoretical (molecular mechanics) and experimental methods (calorimetry and IR spectroscopy). A competition between intra- and intermolecular interactions and effect of steric factor in molecules of organophosphorus compounds were revealed.