Structure and molecular lability of N-(thio)phosphoryl(thio)amides: XL. Interpretation of the N-benzoyl(acetyl)amidothiophosphate→ N-thiobenzoyl(acetyl)amidophosphate rearrangement by means of 1H, 13C, and 31P NMR spectroscopy

Klochkov V.; Zabirov N.; Cherkasov R.; Karataeva F.

Structure and molecular lability of N-(thio)phosphoryl(thio)amides: XL. Interpretation of the N-benzoyl(acetyl)amidothiophosphate→ N-thiobenzoyl(acetyl)amidophosphate rearrangement by means of 1H, 13C, and 31P NMR spectroscopy

Karataeva F.; Cherkasov R.; Zabirov N.; Klochkov V.

URI: https://dspace.kpfu.ru/xmlui/handle/net/134963

Date: 2002

Abstract:

The N-benzoyl(acetyl)amidothiophosphate→ N-thiobenzoyl(acetyl)amidophosphate in CCl4 and toluene-d 8 solutions was studied by means of 1H, 13C, and 31P NMR spectroscopy. The transformation of one amide form to the other is accompanied by intramolecular migrations of the amide proton and (thio)phosphoryl group and is a complex equilibrium of two dynamic systems.

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.