Electrochemical oxidation of hexaalkyldisilanes

Zhuikov V.

Electrochemical oxidation of hexaalkyldisilanes

Zhuikov V.

URI: https://dspace.kpfu.ru/xmlui/handle/net/134924

Date: 1999

Abstract:

Electrochemical oxidation of hexaalkyldisilanes in acetonitrile follows the activation mechanism with cleavage of the Si-Si bond in the overall two-electron process. Oxidation of hexamethyldisilane occurs at a potential 1 V more positive than the standard potential of the process. The standard potential of the leaving group Me3Si+/Me3Si is negative and large in value, which determines the activation character of the whole process. © 1999 MAHK "Hayka/Interperiodica".

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.