The solution of the inverse problem in polarization CARS-spectroscopy

Abstract

An analysis of the solution of the ill-posed inverse problem in polarization CARS is carried out on the basis of mathematical experiments. Smoothing, determination of the number of components and the determination of parameters describing each component are considered. The use of all available experimental and theoretical information is shown to be necessary for correct solution of the problem. The efficiency of the proposed algorithm in the analysis of the complex inhomogeneously broadened lines of chlorocyclohexane is demonstrated. © 1992.