The role of Ni(0) complexes in electrochemical phosphorylation of organic halides Part 1. Factors determining catalytic activity

Abstract

The catalytic efficiency of Ni(0) complexes in coupling reactions of organic and organoelemental halides is shown to be determined by the degree of charge transfer, the value of the electrochemical gap, and the availability or absence of competitive redox reactions. © 1997 Elsevier Science S.A.