FT-IR study of self-association of some hydroperoxides

Abstract

Self-association of cumyl, tertiary butyl and 3-phenylmethyl hydroperoxides in solutions of n-decane, carbon tetrachloride and chlorobenzene were studied by IR spectroscopy (3100-3700 cm-1, 293-353 K). The experimental data were interpreted by factor analysis and band contour resolution. The di-. and trimerization constants and thermodynamic parameters of self-associates were determined. Intramolecular hydrogen bond of cumyl hydroperoxide was investigated. The conformations of tertiary butyl and cumyl hydroperoxides were studied. The solvent influence on the thermodynamic parameters of hydrogen bond was found. © 2004 Elsevier B.V. All rights reserved.