Calculation of spin-lattice relaxation times

Abstract

A general expression is found for the probability for a direct (single-phonon) relaxation transition for arbitrary symmetry of the surroundings of a paramagnetic ion having an effective spin of S = 1/2. The expression is compared with experiment for the case of tetragonal symmetry. Since certain approximations frequently used in the calculations are not used here, a markedly improved agreement is found with the experimental relaxation times. © 1972 Consultants Bureau.