Polarizations, polarizabilities, and conformations of the aryl methyl disulfides

Abstract

1. Each of the aryl methyl disulfides exists in skew conformation with a C-S-S-C dihedral angle of 70-90°. 2. The angle of rotation of the p-XC6H4, fragment relative to the plane of the Car-S-S bonds varies from molecule to molecule, depending on the nature of the X substituent. © 1977 Plenum Publishing Corporation.