Inductive interaction of weak dipoles in unsaturated and aromatic hydrocarbons and their derivatives

Abstract

1. Calculation of induction according to the field effect mechanism is applicable to compounds containing differently hybridized carbon atoms. 2. The "zero" moments of the bonds Csp 3-Csp 2, Csp 3-Csp, and Csp 2-Csp were calculated according to the molecular orbital method as a linear combination of atomic orbitals (MO LCAO). 3. The dipole moments of a number of alkylbenzenes and their chloro-derivatives were calculated, in agreement with the experimental data. 4. An effect of saturation of induction is observed for fluoro-derivatives. © 1968 Consultants Bureau.