New structural type in polybromide-bromometalate hybrids: (Me<inf>3</inf>NH)<inf>3</inf>{[Bi<inf>2</inf>Br<inf>9</inf>](Br<inf>2</inf>)} – Crystal structure and theoretical studies of non-covalent Br ·Br interactions

Fedin V.; Gorokh I.; Novikov A.; Adonin S.; Sokolov M.; Abramov P.

New structural type in polybromide-bromometalate hybrids: (Me<inf>3</inf>NH)<inf>3</inf>{[Bi<inf>2</inf>Br<inf>9</inf>](Br<inf>2</inf>)} – Crystal structure and theoretical studies of non-covalent Br ·Br interactions

Gorokh I.; Adonin S.; Abramov P.; Novikov A.; Sokolov M.; Fedin V.

URI: https://dspace.kpfu.ru/xmlui/handle/net/148633

Date: 2018

Abstract:

© 2018 Elsevier B.V. Reaction between [BiBr6]3− and Br2 in HBr in presence of trimethylammonium bromide results in self-assembly of a supramolecular halometalate-polybromide derivative (Me3NH)3{[Bi2Br9](Br2)} belonging to a novel structural type. DFT calculations allowed estimation of Br⋯Br contact energies (1.3–4.4 kcal/mol).

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.