The reaction of 1,2-diaminoethane with vinylphosphonate occurs as the addition of the amino group to the β-carbon atom of the unsaturated substrate to give 1:1 and 1:2 adducts. The nucleophilic addition of 2-aminoethanol ...

Mixing an excess of 3-methyl-1,2-butadienylphosphonate with 1,2-diaminoethane, 1,2-diaminopropane, or 4,7,10-trioxa-1,13-tridecandiamine leads to the formation of bis- (aminoalkenylphosphonates). Copyright © Taylor & Francis ...