Electrochemical amination of N,N-dimethylaniline

dc.contributor.author	Lisitsyn Y.A.
dc.date.accessioned	2022-02-09T20:48:50Z
dc.date.available	2022-02-09T20:48:50Z
dc.date.issued	2021
dc.identifier.issn	2542-064X
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/170468
dc.description.abstract	The process of indirect cathodic amination of N,N-dimethylaniline using the Ti(IV) – NH2OH system was studied in aqueous solutions of 7–16 M sulfuric acid at 40 °C. An increase in the acid concentration was accompanied by a raise in the efficiency of amine radical cation substitution. In 16 M H2SO4, N,N-dimethyl-p- and N,N-dimethyl-m-phenylenediamines (2:3) were obtained with the total current and dimethylaniline yields of 94% and 100%, respectively. Comparative analysis of the results of amination of N,N-dimethylaniline and aniline in the sulfuric acid media was carried out.
dc.relation.ispartofseries	Uchenye Zapiski Kazanskogo Universiteta. Seriya Estestvennye Nauki
dc.subject	Amine radical cation aromatic substitution
dc.subject	Cathode
dc.subject	Hydroxylamine
dc.subject	N
dc.subject	N-dimethylaniline
dc.subject	Ti(IV)/Ti(III) mediator system
dc.title	Electrochemical amination of N,N-dimethylaniline
dc.type	Article
dc.relation.ispartofseries-issue	1
dc.relation.ispartofseries-volume	163
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	20
dc.source.id	SCOPUS2542064X-2021-163-1-SID85108410759

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.