dc.contributor.author |
Kuchkaev A.M. |
|
dc.contributor.author |
Shmelev N.Y. |
|
dc.contributor.author |
Sukhov A.V. |
|
dc.contributor.author |
Babaev V.M. |
|
dc.contributor.author |
Khayarov K.R. |
|
dc.contributor.author |
Gushchin A.L. |
|
dc.contributor.author |
Sokolov M.N. |
|
dc.contributor.author |
Sinyashin O.G. |
|
dc.contributor.author |
Yakhvarov D.G. |
|
dc.date.accessioned |
2022-02-09T20:45:08Z |
|
dc.date.available |
2022-02-09T20:45:08Z |
|
dc.date.issued |
2021 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/170031 |
|
dc.description.abstract |
Reaction of heterometallic cubane-type cluster complexes—[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba—dibenzylideneacetone, dbbpy—4,4′-di-tert-butyl-2,2′-bipyridine, tu—thiourea, acac—acetylacetonate, py—pyridine, with white phosphorus (P4 ) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4 } has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3 {PdP(OH)3 }S4Cl3 (dbbpy)3 ]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by31P NMR spectroscopy in the reaction mixture. |
|
dc.subject |
Heterometallic cubane-type clusters |
|
dc.subject |
Molybdenum |
|
dc.subject |
Palladium |
|
dc.subject |
Phos-phorous acid |
|
dc.subject |
Phosphine |
|
dc.subject |
White phosphorus |
|
dc.title |
Hydrolysis of element (White) phosphorus under the action of heterometallic cubane-type cluster {mo<inf>3</inf>pds<inf>4</inf>} |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
3 |
|
dc.relation.ispartofseries-volume |
26 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.source.id |
SCOPUS-2021-26-3-SID85100492332 |
|