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dc.contributor.author | Kuchkaev A.M. | |
dc.contributor.author | Shmelev N.Y. | |
dc.contributor.author | Sukhov A.V. | |
dc.contributor.author | Babaev V.M. | |
dc.contributor.author | Khayarov K.R. | |
dc.contributor.author | Gushchin A.L. | |
dc.contributor.author | Sokolov M.N. | |
dc.contributor.author | Sinyashin O.G. | |
dc.contributor.author | Yakhvarov D.G. | |
dc.date.accessioned | 2022-02-09T20:45:08Z | |
dc.date.available | 2022-02-09T20:45:08Z | |
dc.date.issued | 2021 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/170031 | |
dc.description.abstract | Reaction of heterometallic cubane-type cluster complexes—[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba—dibenzylideneacetone, dbbpy—4,4′-di-tert-butyl-2,2′-bipyridine, tu—thiourea, acac—acetylacetonate, py—pyridine, with white phosphorus (P4 ) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4 } has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3 {PdP(OH)3 }S4Cl3 (dbbpy)3 ]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by31P NMR spectroscopy in the reaction mixture. | |
dc.subject | Heterometallic cubane-type clusters | |
dc.subject | Molybdenum | |
dc.subject | Palladium | |
dc.subject | Phos-phorous acid | |
dc.subject | Phosphine | |
dc.subject | White phosphorus | |
dc.title | Hydrolysis of element (White) phosphorus under the action of heterometallic cubane-type cluster {mo<inf>3</inf>pds<inf>4</inf>} | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 3 | |
dc.relation.ispartofseries-volume | 26 | |
dc.collection | Публикации сотрудников КФУ | |
dc.source.id | SCOPUS-2021-26-3-SID85100492332 |