ChAP 1.0: A stationary tropospheric sulfur cycle for Earth system models of intermediate complexity

Abstract

A stationary, computationally efficient scheme ChAP 1.0 (Chemical and Aerosol Processes, version 1.0) for the sulfur cycle in the troposphere is developed. This scheme is designed for Earth system models of intermediate complexity (EMICs). The scheme accounts for sulfur dioxide emissions into the atmosphere, its deposition to the surface, oxidation to sulfates, and dry and wet deposition of sulfates on the surface. The calculations with the scheme are forced by anthropogenic emissions of sulfur dioxide into the atmosphere for 1850-2000 adopted from the CMIP5 dataset and by the ERA-Interim meteorology assuming that natural sources of sulfur into the atmosphere remain unchanged during this period. The ChAP output is compared to changes of the tropospheric sulfur cycle simulations with the CMIP5 data, with the IPCC TAR ensemble, and with the ACCMIP phase II simulations. In addition, in regions of strong anthropogenic sulfur pollution, ChAP results are compared to other data, such as the CAMS reanalysis, EMEP MSC-W, and individual model simulations. Our model reasonably reproduces characteristics of the tropospheric sulfur cycle known from these information sources. In our scheme, about half of the emitted sulfur dioxide is deposited to the surface, and the rest is oxidised into sulfates. In turn, sulfates are mostly removed from the atmosphere by wet deposition. The lifetimes of the sulfur dioxide and sulfates in the atmosphere are close to 1 and 5ĝ€¯d, respectively. The limitations of the scheme are acknowledged, and the prospects for future development are figured out. Despite its simplicity, ChAP may be successfully used to simulate anthropogenic sulfur pollution in the atmosphere at coarse spatial scales and timescales.