Показать сокращенную информацию
dc.contributor.author | Laricheva Y.A. | |
dc.contributor.author | Shmelev N.Y. | |
dc.contributor.author | Gushchin A.L. | |
dc.contributor.author | Sokolov M.N. | |
dc.date.accessioned | 2022-02-09T20:36:03Z | |
dc.date.available | 2022-02-09T20:36:03Z | |
dc.date.issued | 2021 | |
dc.identifier.issn | 1070-3284 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/169309 | |
dc.description.abstract | Abstract: The fabrication of hybrid materials combining the physicochemical properties of various classes is a complicated but promising trend for the development of the modern science. The formation of new hybrid cluster cations [Mo3Pd(C60)S4Cl3(R2Bipy)3]+ and [{Mo3PdS4Cl3(R2Bipy)3}2(C60)]2+ (Bipy is 2,2-bipyridine) containing fullerene C60 coordinated to the palladium atom by the reaction of [Mo3S4Cl3(R2Bipy)3]PF6 with Pd2(Dba)3 (Dba is dibenzylideneacetone) and C60 is shown by a complex of physicochemical methods. The reaction products are studied by IR and NMR (1H, 31Р, and C–H correlations) spectroscopy and mass spectrometry. The quantum-chemical calculations are performed by the DFT method for the correct interpretation of the spectroscopic data and elucidation of the electronic structures of the fullerene-containing compounds. | |
dc.relation.ispartofseries | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya | |
dc.subject | cluster complexes | |
dc.subject | DFT calculations | |
dc.subject | fullerene | |
dc.subject | molybdenum | |
dc.subject | palladium | |
dc.title | Study of the Reactions of Fullerene С<inf>60</inf> with the Palladium-Containing Clusters of Molybdenum {Mo<inf>3</inf>PdS<inf>4</inf>} by Spectroscopic and Calculation Methods | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 3 | |
dc.relation.ispartofseries-volume | 47 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 196 | |
dc.source.id | SCOPUS10703284-2021-47-3-SID85102953196 |