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Study of the Reactions of Fullerene С<inf>60</inf> with the Palladium-Containing Clusters of Molybdenum {Mo<inf>3</inf>PdS<inf>4</inf>} by Spectroscopic and Calculation Methods

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dc.contributor.author Laricheva Y.A.
dc.contributor.author Shmelev N.Y.
dc.contributor.author Gushchin A.L.
dc.contributor.author Sokolov M.N.
dc.date.accessioned 2022-02-09T20:36:03Z
dc.date.available 2022-02-09T20:36:03Z
dc.date.issued 2021
dc.identifier.issn 1070-3284
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/169309
dc.description.abstract Abstract: The fabrication of hybrid materials combining the physicochemical properties of various classes is a complicated but promising trend for the development of the modern science. The formation of new hybrid cluster cations [Mo3Pd(C60)S4Cl3(R2Bipy)3]+ and [{Mo3PdS4Cl3(R2Bipy)3}2(C60)]2+ (Bipy is 2,2-bipyridine) containing fullerene C60 coordinated to the palladium atom by the reaction of [Mo3S4Cl3(R2Bipy)3]PF6 with Pd2(Dba)3 (Dba is dibenzylideneacetone) and C60 is shown by a complex of physicochemical methods. The reaction products are studied by IR and NMR (1H, 31Р, and C–H correlations) spectroscopy and mass spectrometry. The quantum-chemical calculations are performed by the DFT method for the correct interpretation of the spectroscopic data and elucidation of the electronic structures of the fullerene-containing compounds.
dc.relation.ispartofseries Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
dc.subject cluster complexes
dc.subject DFT calculations
dc.subject fullerene
dc.subject molybdenum
dc.subject palladium
dc.title Study of the Reactions of Fullerene С<inf>60</inf> with the Palladium-Containing Clusters of Molybdenum {Mo<inf>3</inf>PdS<inf>4</inf>} by Spectroscopic and Calculation Methods
dc.type Article
dc.relation.ispartofseries-issue 3
dc.relation.ispartofseries-volume 47
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 196
dc.source.id SCOPUS10703284-2021-47-3-SID85102953196


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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