dc.contributor.author |
Bakhtiyarov D.I. |
|
dc.contributor.author |
Romanov S.R. |
|
dc.contributor.author |
Hafizova A.I. |
|
dc.contributor.author |
Shibaeva K.O. |
|
dc.contributor.author |
Gerasimov A.V. |
|
dc.contributor.author |
Bakhtiyarova Y.V. |
|
dc.contributor.author |
Usupova L.M. |
|
dc.contributor.author |
Galkina I.V. |
|
dc.date.accessioned |
2022-02-09T20:35:19Z |
|
dc.date.available |
2022-02-09T20:35:19Z |
|
dc.date.issued |
2021 |
|
dc.identifier.issn |
1042-6507 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/169228 |
|
dc.description.abstract |
The processes of complexation of dicarboxylate diphosphabetaines with gadolinium nitrate were studied, as a result of which stable polymer metal complexes insoluble in inorganic and organic solvents were obtained. To carry out these reactions, dicarboxylate diphosphabetaines were previously synthesized: 3,3'-(propane-1,3-diylbis (diphenyl)phosphoniondiyl)dipropanoate and 3,3'-(hexane-1,3-diylbis (diphenyl)phosphoniondiyl)dipropanoate, based on maleic acid with 1,3-bis(diphenylphosphino)bisphosphinspropane and 1,6-bis(diphenylphosphino)bisphosphinshexane. The structure of dicarboxylate diphosphabetaines and poly-nuclear polymer complexes of gadolinium has been confirmed by modern physical and chemical methods of research, including NMR and IR spectra, elemental and X-ray structural analysis, thermal stability has been studied by simultaneous thermogravimetry and differential scanning calorimetry. |
|
dc.relation.ispartofseries |
Phosphorus, Sulfur and Silicon and the Related Elements |
|
dc.subject |
dicarboxylate diphosphabetaines |
|
dc.subject |
Gadolinium complexes |
|
dc.subject |
tertiary phosphines |
|
dc.subject |
thermal stability |
|
dc.subject |
X-ray crystallography |
|
dc.title |
New complexes of gadolinium with dicarboxylate diphosphabetaines |
|
dc.type |
Article |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.source.id |
SCOPUS10426507-2021-SID85121335664 |
|