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Thermochemistry of solution, solvation and hydrogen bonding of linear and cyclic ethers in solvents

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dc.contributor.author Rakipov I.T.
dc.contributor.author Semenov K.N.
dc.contributor.author Petrov A.A.
dc.contributor.author Akhmadiyarov A.A.
dc.contributor.author Khachatrian A.A.
dc.contributor.author Fakhurtdinova A.R.
dc.contributor.author Solomonov B.N.
dc.date.accessioned 2022-02-09T20:32:17Z
dc.date.available 2022-02-09T20:32:17Z
dc.date.issued 2021
dc.identifier.issn 0040-6031
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/168842
dc.description.abstract In work a thermochemistry of solution, solvation and hydrogen bond formation of linear (diethyl ether and diglyme) and cyclic ethers (1,4-dioxane, 12-crown-4, 15-crown-5 and 18-crown-6) in proton acceptor and proton donor solvents were studied. The infinite dilution solution enthalpies of ethers in cyclohexane, carbon tetrachloride, benzene, ethyl acetate, N,N-dimethylformamide, dimethylsulfoxide, acetone, pyridine, chloroform and methanol were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of ethers in the solvent are calculated. The influence of number of active centers in ethers on thermochemical parameters is shown. It was found that the formation of hydrogen bonds for linear and cyclic ethers with proton donors are different.
dc.relation.ispartofseries Thermochimica Acta
dc.subject Intermolecular interaction
dc.subject Linear and cyclic ethers
dc.subject Proton acceptors
dc.subject Proton donors
dc.subject Solution calorimetry
dc.subject Solution enthalpies
dc.title Thermochemistry of solution, solvation and hydrogen bonding of linear and cyclic ethers in solvents
dc.type Article
dc.relation.ispartofseries-volume 700
dc.collection Публикации сотрудников КФУ
dc.source.id SCOPUS00406031-2021-700-SID85103686792


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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