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PROPIOLATE CLUSTER COMPLEXES (Bu<inf>4</inf>N)<inf>2</inf>[Mo<inf>6</inf> X <inf>8</inf>(OOC–C≡CH)<inf>6</inf>] (X = Br, I)

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dc.contributor.author Mikhailov M.A.
dc.contributor.author Berezin A.S.
dc.contributor.author Sukhikh T.S.
dc.contributor.author Sheven’ D.G.
dc.contributor.author Gushchin A.L.
dc.contributor.author Sokolov M.N.
dc.date.accessioned 2022-02-09T20:31:29Z
dc.date.available 2022-02-09T20:31:29Z
dc.date.issued 2021
dc.identifier.issn 0022-4766
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/168744
dc.description.abstract Abstract: Two new cluster complexes (Bu4N)2[Mo6X8(OOC–C≡CH)6] (1) (X = Br) and (2) (X = I) are synthesized by the reaction of (Bu4N)2[Mo6X8(OOCCH3)6] (X = Br, I) with HOOC–C≡CH propiolic acid, their crystal structures are determined, and the luminescent properties are studied for powder samples at different temperatures. According to X-ray crystallographic data, molybdenum atoms are monodentately coordinated by oxygen atoms of the carboxyl group at Mo–O distances of 2.108(2)-2.121(16) Å. The propiolate complexes are characterized by electrospray mass spectrometry, 1Н and 13С NMR, elemental analysis, and IR spectroscopy. [Figure not available: see fulltext.]
dc.relation.ispartofseries Journal of Structural Chemistry
dc.subject bromides
dc.subject clusters
dc.subject electrochemistry
dc.subject iodides
dc.subject luminescence
dc.subject molybdenum
dc.subject propiolate complexes
dc.subject X-ray crystallographic analysis
dc.title PROPIOLATE CLUSTER COMPLEXES (Bu<inf>4</inf>N)<inf>2</inf>[Mo<inf>6</inf> X <inf>8</inf>(OOC–C≡CH)<inf>6</inf>] (X = Br, I)
dc.type Article
dc.relation.ispartofseries-issue 12
dc.relation.ispartofseries-volume 62
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1896
dc.source.id SCOPUS00224766-2021-62-12-SID85121734276


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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