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The role of organonickel reagents in organophosphorus chemistry

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dc.contributor.author Gafurov Z.N.
dc.contributor.author Kagilev A.A.
dc.contributor.author Kantyukov A.O.
dc.contributor.author Sinyashin O.G.
dc.contributor.author Yakhvarov D.G.
dc.date.accessioned 2022-02-09T20:30:47Z
dc.date.available 2022-02-09T20:30:47Z
dc.date.issued 2021
dc.identifier.issn 0010-8545
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/168661
dc.description.abstract Organonickel reagents are widely used for the obtaining of the organophosphorus compounds from different phosphorus sources including elemental white phosphorus, phosphorus trichloride and phosphine PH3. In particular, new highly efficient and environmentally friendly methods for preparation of organophosphorus compounds bearing phosphorus–carbon bonds have been elaborated using the electrochemically generated organonickel complexes. The synthetic application of the developed techniques towards the formation of wide range of practically important primary, secondary and tertiary organophosphines, with a special focus on unsymmetrical PH phosphines, is disclosed. The mechanistic pathways and the structure of the assumed intermediates formed on some key stages of the overall process are presented for discussion. The elaborated methods operate on the electrochemical techniques with combination of coordination chemistry principles and are considered as an efficient alternative to the more common methods.
dc.relation.ispartofseries Coordination Chemistry Reviews
dc.subject Electrochemistry
dc.subject Electrosynthesis
dc.subject Nickel complexes
dc.subject Organonickel reagents
dc.subject Organophosphorus compounds
dc.subject Secondary and tertiary organophosphines
dc.subject White phosphorus
dc.title The role of organonickel reagents in organophosphorus chemistry
dc.type Review
dc.relation.ispartofseries-volume 438
dc.collection Публикации сотрудников КФУ
dc.source.id SCOPUS00108545-2021-438-SID85103114751


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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