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Mono- And bisphenanthroline complexes of chromium group metals with conjugated heterodienes – A theoretical and experimental study

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dc.contributor.author Galimullin R.N.
dc.contributor.author Plotnikova A.V.
dc.contributor.author Kolpakova E.V.
dc.contributor.author Kuramshin A.I.
dc.date.accessioned 2021-02-26T20:51:19Z
dc.date.available 2021-02-26T20:51:19Z
dc.date.issued 2020
dc.identifier.issn 2542-064X
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/163252
dc.description.abstract © 2020 Kazan Federal University. All rights reserved. A theoretical study was carried out (with the help of the density functional method, based on LANL2DZ and the modified BHandHLYP functional) for the energy, electronic, and geometric properties of (heterodien)M(phen)(CO)2 and (heterodien)M(phen)2 complexes. The obtained results indicate the possibility of using phenanthroline ligand to stabilize heterodiene structures. A number of previously undescribed carbonylphenanthroline, bis-phenanthroline carbonyl, oxodien- and thioxodienfenanthroline (and bis-phenanthroline oxodien/thioxodien) coordination compounds were synthesized. A low lability of the phenolanthroline-stabilized organometallic compound was demonstrated by the NMR studies. The prospects of applying phenanthroline as a “ligand standard” to synthesize organometallic compounds of VI-group metals were confirmed. Dimethylphosphite was added via a multiple C=O bond of the oxodiene and dienone complexes of the chromium group metals.
dc.relation.ispartofseries Uchenye Zapiski Kazanskogo Universiteta. Seriya Estestvennye Nauki
dc.subject 1,10-phenanthroline
dc.subject Chromium group complexes
dc.subject Heterodienes
dc.subject Quantum chemical calculations
dc.title Mono- And bisphenanthroline complexes of chromium group metals with conjugated heterodienes – A theoretical and experimental study
dc.type Article
dc.relation.ispartofseries-issue 1
dc.relation.ispartofseries-volume 162
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 17
dc.source.id SCOPUS2542064X-2020-162-1-SID85092934836


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  • Публикации сотрудников КФУ Scopus [22633]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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