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The formation of mesitylphosphine and dimesitylphosphine in the reaction of organonickel σ-complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine) with phosphine PH<inf>3</inf>
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| dc.contributor.author | Gafurov Z.N. | |
| dc.contributor.author | Sakhapov I.F. | |
| dc.contributor.author | Kagilev A.A. | |
| dc.contributor.author | Kantyukov A.O. | |
| dc.contributor.author | Khayarov K.R. | |
| dc.contributor.author | Sinyashin O.G. | |
| dc.contributor.author | Yakhvarov D.G. | |
| dc.date.accessioned | 2021-02-26T20:37:15Z | |
| dc.date.available | 2021-02-26T20:37:15Z | |
| dc.date.issued | 2020 | |
| dc.identifier.issn | 1042-6507 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/163046 | |
| dc.description.abstract | © 2020, © 2020 Taylor & Francis Group, LLC. The reactivity of the previously reported organonickel σ-complex [NiBr(Mes)(bpy)], where Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine, toward phosphine PH3 was investigated. The reaction leads to primary mesitylphosphine MesPH2 as the main product and dimesitylphosphine Mes2PH as secondary product with the nickel complex as transmetalating agent. The formed MesPH2 reacts with an excess of the complex giving Mes2PH as the major product. | |
| dc.relation.ispartofseries | Phosphorus, Sulfur and Silicon and the Related Elements | |
| dc.subject | dimesitylphosphine | |
| dc.subject | mesitylphosphine | |
| dc.subject | organonickel σ-complexes | |
| dc.subject | Phosphine PH 3 | |
| dc.subject | transmetalation | |
| dc.title | The formation of mesitylphosphine and dimesitylphosphine in the reaction of organonickel σ-complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine) with phosphine PH<inf>3</inf> | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 9 | |
| dc.relation.ispartofseries-volume | 195 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 726 | |
| dc.source.id | SCOPUS10426507-2020-195-9-SID85083764770 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.