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The formation of mesitylphosphine and dimesitylphosphine in the reaction of organonickel σ-complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine) with phosphine PH<inf>3</inf>

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dc.contributor.author Gafurov Z.N.
dc.contributor.author Sakhapov I.F.
dc.contributor.author Kagilev A.A.
dc.contributor.author Kantyukov A.O.
dc.contributor.author Khayarov K.R.
dc.contributor.author Sinyashin O.G.
dc.contributor.author Yakhvarov D.G.
dc.date.accessioned 2021-02-26T20:37:15Z
dc.date.available 2021-02-26T20:37:15Z
dc.date.issued 2020
dc.identifier.issn 1042-6507
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/163046
dc.description.abstract © 2020, © 2020 Taylor & Francis Group, LLC. The reactivity of the previously reported organonickel σ-complex [NiBr(Mes)(bpy)], where Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine, toward phosphine PH3 was investigated. The reaction leads to primary mesitylphosphine MesPH2 as the main product and dimesitylphosphine Mes2PH as secondary product with the nickel complex as transmetalating agent. The formed MesPH2 reacts with an excess of the complex giving Mes2PH as the major product.
dc.relation.ispartofseries Phosphorus, Sulfur and Silicon and the Related Elements
dc.subject dimesitylphosphine
dc.subject mesitylphosphine
dc.subject organonickel σ-complexes
dc.subject Phosphine PH 3
dc.subject transmetalation
dc.title The formation of mesitylphosphine and dimesitylphosphine in the reaction of organonickel σ-complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine) with phosphine PH<inf>3</inf>
dc.type Article
dc.relation.ispartofseries-issue 9
dc.relation.ispartofseries-volume 195
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 726
dc.source.id SCOPUS10426507-2020-195-9-SID85083764770


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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