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Photopolymerized two-dimensional organic films with calix[4]arene scaffold

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dc.contributor.author Semenok D.
dc.contributor.author Kletskov A.
dc.contributor.author Burilov V.
dc.contributor.author Luchkin S.
dc.contributor.author Potkin V.
dc.contributor.author Lukin O.
dc.date.accessioned 2021-02-25T20:56:16Z
dc.date.available 2021-02-25T20:56:16Z
dc.date.issued 2020
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/162726
dc.description.abstract © 2020 Elsevier Ltd A series of 14 macromolecular derivatives of resorcinarenes and thiacalix[4]arenes bearing alkyl chains (up to -C11H23) and different photoreactive groups (chalcone sulfonyl, naphthyl (Np), alkyl azide (Alk-N3)) was synthesized. The obtained compounds were used to design monomolecular 2D films by the Langmuir-Blodgett method at the air/water interface using ultraviolet-assisted covalent crosslinking. It was found that the alkyl azide derivatives can effectively form cross-copolymerized two-dimensional films with the thickness of 0.8-1.5 nm, which was revealed with the help of atomic force topography. A controversial effect of UV irradiation on the film topography, namely, ordering and disordering of the film structure, was observed. The effect of donor and acceptor substituents in styrene ring of chalcone sulfonyl (carbonyl) chlorides on the wetting angle of the films and its dependence on concentration of voids in a coating, were also studied. It was found that the most ordered 2D structures are formed for compounds with a sterically balanced set of substituents.
dc.subject Azides
dc.subject Calix[4]arenes
dc.subject Chalcones
dc.subject Langmuir-Blodget
dc.subject Photopolymerization
dc.subject Resorcinarenes
dc.subject Thiacalix[4]arenes
dc.subject Two-dimensional organic films
dc.title Photopolymerized two-dimensional organic films with calix[4]arene scaffold
dc.type Article
dc.relation.ispartofseries-volume 25
dc.collection Публикации сотрудников КФУ
dc.source.id SCOPUS-2020-25-SID85087057739


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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