dc.contributor.author |
Shekurov R. |
|
dc.contributor.author |
Khrizanforov M. |
|
dc.contributor.author |
Gerasimova T. |
|
dc.contributor.author |
Yamaleeva Z. |
|
dc.contributor.author |
Ivshin K. |
|
dc.contributor.author |
Lakomkina A. |
|
dc.contributor.author |
Bezkishko I. |
|
dc.contributor.author |
Kononov A. |
|
dc.contributor.author |
Sinyashin O. |
|
dc.contributor.author |
Budnikova Y. |
|
dc.contributor.author |
Kataeva O. |
|
dc.contributor.author |
Miluykov V. |
|
dc.date.accessioned |
2021-02-25T20:56:15Z |
|
dc.date.available |
2021-02-25T20:56:15Z |
|
dc.date.issued |
2020 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/162723 |
|
dc.description.abstract |
© 2020 by the authors. The reaction of triferrocenylthiophosphite with elemental sulfur leads to triferrocenyltetrathiophosphate. The molecule of tetrathiophosphate adopts propeller-like all synclinal-conformation of the ferrocenyl fragments respective to the P=S bond. All ferrocenyl groups have nearly ideal eclipsed conformation of the cyclopentadienyl fragments. The Fc3S3P (1), Fc3S3P=O, (2) and Fc3S3P=S (3) demonstrate three reversible and well-separated ferrocenyl-based redox events. The electronic structures of 1-3 have been studied quantum-chemically; the energies and composition of frontier orbitals have been calculated. |
|
dc.subject |
Cyclic voltammetry |
|
dc.subject |
DFT calculations |
|
dc.subject |
Multi-ferrocenyl compounds |
|
dc.subject |
Phosphorus thioesters |
|
dc.subject |
Tetrathiophosphate |
|
dc.title |
Electrochemical properties and structure of multi-ferrocenyl phosphorus thioesters |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
4 |
|
dc.relation.ispartofseries-volume |
25 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.source.id |
SCOPUS-2020-25-4-SID85079906497 |
|