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dc.contributor.author | Shekurov R. | |
dc.contributor.author | Khrizanforov M. | |
dc.contributor.author | Gerasimova T. | |
dc.contributor.author | Yamaleeva Z. | |
dc.contributor.author | Ivshin K. | |
dc.contributor.author | Lakomkina A. | |
dc.contributor.author | Bezkishko I. | |
dc.contributor.author | Kononov A. | |
dc.contributor.author | Sinyashin O. | |
dc.contributor.author | Budnikova Y. | |
dc.contributor.author | Kataeva O. | |
dc.contributor.author | Miluykov V. | |
dc.date.accessioned | 2021-02-25T20:56:15Z | |
dc.date.available | 2021-02-25T20:56:15Z | |
dc.date.issued | 2020 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/162723 | |
dc.description.abstract | © 2020 by the authors. The reaction of triferrocenylthiophosphite with elemental sulfur leads to triferrocenyltetrathiophosphate. The molecule of tetrathiophosphate adopts propeller-like all synclinal-conformation of the ferrocenyl fragments respective to the P=S bond. All ferrocenyl groups have nearly ideal eclipsed conformation of the cyclopentadienyl fragments. The Fc3S3P (1), Fc3S3P=O, (2) and Fc3S3P=S (3) demonstrate three reversible and well-separated ferrocenyl-based redox events. The electronic structures of 1-3 have been studied quantum-chemically; the energies and composition of frontier orbitals have been calculated. | |
dc.subject | Cyclic voltammetry | |
dc.subject | DFT calculations | |
dc.subject | Multi-ferrocenyl compounds | |
dc.subject | Phosphorus thioesters | |
dc.subject | Tetrathiophosphate | |
dc.title | Electrochemical properties and structure of multi-ferrocenyl phosphorus thioesters | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 4 | |
dc.relation.ispartofseries-volume | 25 | |
dc.collection | Публикации сотрудников КФУ | |
dc.source.id | SCOPUS-2020-25-4-SID85079906497 |