Показать сокращенную информацию
dc.contributor.author | Mironova A.D. | |
dc.contributor.author | Mikhailov M.A. | |
dc.contributor.author | Brylev K.A. | |
dc.contributor.author | Gushchin A.L. | |
dc.contributor.author | Sukhikh T.S. | |
dc.contributor.author | Sokolov M.N. | |
dc.date.accessioned | 2021-02-25T20:39:03Z | |
dc.date.available | 2021-02-25T20:39:03Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 1144-0546 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/162170 | |
dc.description.abstract | © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. (Bu4N)2[Mo6I8(N3)6], prepared in a clean high-yield reaction from (Bu4N)2[Mo6I8(CH3COO)6] and Me3SiN3, undergoes [3+2] cycloaddition with CH3O(O)CC(O)OCH3 with the formation of a novel hexakis(triazolate) complex, (Bu4N)2[Mo6I8(N3C2(COOCH3)2)6] with symmetrically coordinated 4,5-di(carbmethoxy)triazol-2-yl ligands. The product was characterized by X-ray analysis, NMR, IR and ESI-mass spectrometry. It undergoes a quasi reversible oxidation in CH3CN at E1/2 = 1.36 V (vs. Ag/AgCl) and is red-light emissive upon UV photoexcitation. Reaction with methylpropiolate also yields a corresponding hexakis(triazolate) complex, [Mo6I8(N3C2H(COOCH3))6]2-, which exists as a 1:1 mixture of two isomers. Alkynes that lacking strongly electron-withdrawing substituents fail to undergo the cycloaddition reaction. This journal is | |
dc.relation.ispartofseries | New Journal of Chemistry | |
dc.title | Phosphorescent complexes of {Mo<inf>6</inf>I<inf>8</inf>}<sup>4+</sup>with triazolates: [2+3] cycloaddition of alkynes to [Mo<inf>6</inf>I<inf>8</inf>(N<inf>3</inf>)<inf>6</inf>]<sup>2-</sup> | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 47 | |
dc.relation.ispartofseries-volume | 44 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 20620 | |
dc.source.id | SCOPUS11440546-2020-44-47-SID85098084770 |