dc.contributor.author |
Mironova A.D. |
|
dc.contributor.author |
Mikhailov M.A. |
|
dc.contributor.author |
Brylev K.A. |
|
dc.contributor.author |
Gushchin A.L. |
|
dc.contributor.author |
Sukhikh T.S. |
|
dc.contributor.author |
Sokolov M.N. |
|
dc.date.accessioned |
2021-02-25T20:39:03Z |
|
dc.date.available |
2021-02-25T20:39:03Z |
|
dc.date.issued |
2020 |
|
dc.identifier.issn |
1144-0546 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/162170 |
|
dc.description.abstract |
© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. (Bu4N)2[Mo6I8(N3)6], prepared in a clean high-yield reaction from (Bu4N)2[Mo6I8(CH3COO)6] and Me3SiN3, undergoes [3+2] cycloaddition with CH3O(O)CC(O)OCH3 with the formation of a novel hexakis(triazolate) complex, (Bu4N)2[Mo6I8(N3C2(COOCH3)2)6] with symmetrically coordinated 4,5-di(carbmethoxy)triazol-2-yl ligands. The product was characterized by X-ray analysis, NMR, IR and ESI-mass spectrometry. It undergoes a quasi reversible oxidation in CH3CN at E1/2 = 1.36 V (vs. Ag/AgCl) and is red-light emissive upon UV photoexcitation. Reaction with methylpropiolate also yields a corresponding hexakis(triazolate) complex, [Mo6I8(N3C2H(COOCH3))6]2-, which exists as a 1:1 mixture of two isomers. Alkynes that lacking strongly electron-withdrawing substituents fail to undergo the cycloaddition reaction. This journal is |
|
dc.relation.ispartofseries |
New Journal of Chemistry |
|
dc.title |
Phosphorescent complexes of {Mo<inf>6</inf>I<inf>8</inf>}<sup>4+</sup>with triazolates: [2+3] cycloaddition of alkynes to [Mo<inf>6</inf>I<inf>8</inf>(N<inf>3</inf>)<inf>6</inf>]<sup>2-</sup> |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
47 |
|
dc.relation.ispartofseries-volume |
44 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
20620 |
|
dc.source.id |
SCOPUS11440546-2020-44-47-SID85098084770 |
|