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Uncharged water-soluble amide derivatives of pillar[5]arene: synthesis and supramolecular self-assembly with tetrazole-containing polymers

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dc.contributor.author Shurpik D.N.
dc.contributor.author Nazarova A.A.
dc.contributor.author Makhmutova L.I.
dc.contributor.author Kizhnyaev V.N.
dc.contributor.author Stoikov I.I.
dc.date.accessioned 2021-02-25T20:37:58Z
dc.date.available 2021-02-25T20:37:58Z
dc.date.issued 2020
dc.identifier.issn 1066-5285
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/162113
dc.description.abstract © 2020, Springer Science+Business Media, Inc. New uncharged water-soluble pillar[5]arene derivatives bearing 2-hydroxyethylamide and 2-hydroxypropylamide moieties have been for the fi rst time synthesized via aminolysis. A detailed analysis performed for the spectral data (UV, IR; and 1H, 13C, NOESY, and HSQC NMR) allowed us to determine the spatial structure of the synthesized macrocycles. Aggregation properties of the obtained compounds with water-soluble tetrazole-containing polymers, viz. poly-5-vinyltetrazole (PVT) and polyvinyl(tetrazolyl)ethyl ether (PVTE), were evaluated. Pillar[5]-arene containing 2-hydroxyethylamide moieties formed monodisperse nanoscale aggregates with an average hydrodynamic diameter of 117 nm in the presence of PVTE in aqueous solution. The morphology of resulting particles was determined by scanning electron microscopy.
dc.relation.ispartofseries Russian Chemical Bulletin
dc.subject macrocycles
dc.subject pillar[5]arene
dc.subject self-assembly
dc.subject self-organization
dc.subject supramo-lecular chemistry
dc.subject water-soluble synthetic receptors
dc.title Uncharged water-soluble amide derivatives of pillar[5]arene: synthesis and supramolecular self-assembly with tetrazole-containing polymers
dc.type Article
dc.relation.ispartofseries-issue 1
dc.relation.ispartofseries-volume 69
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 97
dc.source.id SCOPUS10665285-2020-69-1-SID85083308682


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  • Публикации сотрудников КФУ Scopus [22633]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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