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dc.contributor.author | Falin M. | |
dc.contributor.author | Latypov V. | |
dc.contributor.author | Leushin A. | |
dc.contributor.author | Safiullin G. | |
dc.contributor.author | Shakirov A. | |
dc.contributor.author | Shavelev A. | |
dc.date.accessioned | 2021-02-25T20:35:34Z | |
dc.date.available | 2021-02-25T20:35:34Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0925-8388 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/161916 | |
dc.description.abstract | © 2019 Elsevier B.V. EPR and optical spectroscopy of trigonal Yb3+ centers in LiCaAlF6 are reported. The results of these experiments make it possible to conclude that Yb3+ ions replace host cation sites Ca2+ forming mainly one type of paramagnetic center of trigonal symmetry. Positions of lines in optical spectra were specified of the observed center. The crystal field parameters of trigonal center Yb3+ were determined. Structural models of the observed center are proposed. It is shown that the substitution of the Yb3+ ion for the Ca2+ ion leads to the considerable compression of the YbF6 octahedron along the trigonal axis of the center. | |
dc.relation.ispartofseries | Journal of Alloys and Compounds | |
dc.subject | crystal field | |
dc.subject | Crystal growth | |
dc.subject | Energy levels | |
dc.subject | EPR and optical spectroscopy | |
dc.subject | Insulators | |
dc.subject | LiCaAlF 6 | |
dc.subject | Yb ion 3+ | |
dc.title | EPR and optical spectroscopy of Yb<sup>3+</sup> ions in LiCaAlF<inf>6</inf> single crystals | |
dc.type | Article | |
dc.relation.ispartofseries-volume | 812 | |
dc.collection | Публикации сотрудников КФУ | |
dc.source.id | SCOPUS09258388-2020-812-SID85072087772 |