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Study of all stages of the Diels–Alder reaction of cyclopentadiene with 2,3-dicyano-1,4-benzoquinone and monoadducts: Kinetics, thermochemistry, and high pressure effect

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dc.contributor.author Kolesnikova A.O.
dc.contributor.author Kornilov D.A.
dc.contributor.author Gubaidullin A.T.
dc.contributor.author Kiselev V.D.
dc.date.accessioned 2021-02-25T20:35:09Z
dc.date.available 2021-02-25T20:35:09Z
dc.date.issued 2020
dc.identifier.issn 0538-8066
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/161871
dc.description.abstract © 2020 Wiley Periodicals, Inc. The kinetic parameters and enthalpies of the Diels–Alder reactions between cyclopentadiene and 2,3-dicyano-1,4-benzoquinone leading to the formation of two different monoadducts and bisadduct were determined. The stability of adducts is compared. Monoadduct appears to be thermodynamically more stable than the bisadduct. Comparison with the other Diels–Alder reactions studied previously allows us to conclude that the heat effects upon formation of the considered Diels–Alder adducts are the lowest in comparison with all the studied dienophiles.
dc.relation.ispartofseries International Journal of Chemical Kinetics
dc.subject 2,3-dicyano-1,4-benzoquinone
dc.subject cyclopentadiene
dc.subject Diels-Alder reaction
dc.subject high pressure effect
dc.subject kinetics
dc.subject thermochemistry
dc.title Study of all stages of the Diels–Alder reaction of cyclopentadiene with 2,3-dicyano-1,4-benzoquinone and monoadducts: Kinetics, thermochemistry, and high pressure effect
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 52
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 301
dc.source.id SCOPUS05388066-2020-52-5-SID85082293748


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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