dc.contributor.author |
Novikov V. |
|
dc.contributor.author |
Yamaleev I. |
|
dc.contributor.author |
Varfolomeev M. |
|
dc.date.accessioned |
2021-02-25T20:33:17Z |
|
dc.date.available |
2021-02-25T20:33:17Z |
|
dc.date.issued |
2020 |
|
dc.identifier.issn |
0040-6031 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/161700 |
|
dc.description.abstract |
© 2019 Elsevier B.V. Vaporization/sublimation enthalpies for twenty-one disubstituted benzenes were calculated from dissolution enthalpies and solvation enthalpies in four solvents of different polarity: carbon tetrachloride, benzene, N,N-dimethylformamide, and acetonitrile. The values of solvation enthalpy were calculated using group-additivity scheme for each solvent. Dissolution enthalpies of some substances were taken from literature and fifty-six original values were measured in the present work. The calculated values of vaporization/sublimation enthalpy were compared with the literature data. It was concluded that calculated vaporization/sublimation enthalpies do not depend on the choice of solvents excluding those that interact with the solute specifically. |
|
dc.relation.ispartofseries |
Thermochimica Acta |
|
dc.subject |
Disubstituted benzenes |
|
dc.subject |
Enthalpy of dissolution |
|
dc.subject |
Enthalpy of sublimation |
|
dc.subject |
Enthalpy of vaporization |
|
dc.subject |
Group-contributions |
|
dc.title |
Verification of solution calorimetry approach for determination of vaporization and sublimation enthalpies in different solvents: Example of disubstituted benzenes |
|
dc.type |
Article |
|
dc.relation.ispartofseries-volume |
685 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.source.id |
SCOPUS00406031-2020-685-SID85078863807 |
|