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The role of calix[n]arenes and pillar[n]arenes in the design of silver nanoparticles: Self-assembly and application

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dc.contributor.author Padnya P.
dc.contributor.author Gorbachuk V.
dc.contributor.author Stoikov I.
dc.date.accessioned 2021-02-25T06:40:11Z
dc.date.available 2021-02-25T06:40:11Z
dc.date.issued 2020
dc.identifier.issn 1661-6596
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/160959
dc.description.abstract © 2020 by the authors. Licensee MDPI, Basel, Switzerland. Silver nanoparticles (AgNPs) are an attractive alternative to plasmonic gold nanoparticles. The relative cheapness and redox stability determine the growing interest of researchers in obtaining selective plasmonic and electrochemical (bio)sensors based on silver nanoparticles. The controlled synthesis of metal nanoparticles of a defined morphology is a nontrivial task, important for such fields as biochemistry, catalysis, biosensors and microelectronics. Cyclophanes are well known for their great receptor properties and are of particular interest in the creation of metal nanoparticles due to a variety of cyclophane 3D structures and unique redox abilities. Silver ion-based supramolecular assemblies are attractive due to the possibility of reduction by “soft” reducing agents as well as being accessible precursors for silver nanoparticles of predefined morphology, which are promising for implementation in plasmonic sensors. For this purpose, the chemistry of cyclophanes offers a whole arsenal of approaches: exocyclic ion coordination, association, stabilization of the growth centers of metal nanoparticles, as well as in reduction of silver ions. Thus, this review presents the recent advances in the synthesis and stabilization of Ag (0) nanoparticles based on self-assembly of associates with Ag (I) ions with the participation of bulk platforms of cyclophanes (resorcin[4]arenes, (thia)calix[n]arenes, pillar[n]arenes).
dc.relation.ispartofseries International Journal of Molecular Sciences
dc.subject Calix[n]arenes
dc.subject Cyclophanes
dc.subject Pillar[n]arenes
dc.subject Resorcin[4]arenes
dc.subject Self-assembly
dc.subject Silver nanoparticles
dc.subject Thiacalix[n]arenes
dc.title The role of calix[n]arenes and pillar[n]arenes in the design of silver nanoparticles: Self-assembly and application
dc.type Review
dc.relation.ispartofseries-issue 4
dc.relation.ispartofseries-volume 21
dc.collection Публикации сотрудников КФУ
dc.source.id SCOPUS16616596-2020-21-4-SID85079900243


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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